The IV Line News from the Lab
Inorganic Ventures' E-newsletter  •  August 2004  •  ivstandards.com
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In this issue...
 News from the Lab  Articles Online
 Analytical Quick Tip  Joke of the Month
 The Truth About Expiration Dates

»  What would you like to see in future issues? Suggestions are welcome.

»  Recommend the IV Line to a friend or colleague.


71-Element Standards Set

News from the Lab

New! 71-Element Set
Multiple-Application ICP-MS Standards Set
Inorganic Ventures is the first to introduce the most complete, versatile and stable ICP-MS multi-element set. View the set details for an elemental breakdown.
On sale through August 31st!

Reduced Pricing
New pricing on Multi-Element Sets
We've lowered our prices on two of our most popular multi-element standard sets: CCS-SET & CMS-SET. Click here for details.

Analytical Quick Tip

When using chemical standard solutions, be sure to screw the cap on tightly after use and do not leave the cap off the bottle for more than a few seconds. An aqueous standard solution with a loose cap will concentrate itself through transpiration by evaporation by several % in only a few weeks.

The Truth About Expiration Dates

Expiration Date is the recommended amount of time that a standard should remain in use in a laboratory setting after it has been opened. Inevitably, something will go wrong with the standard due to transpiration, cross-contamination, and/or human error. Most federal and state regulatory agencies recommend expiration dates no longer than 1 year. Some require as little as 6 months.

The expiration dates of trace metals standards are dependent upon:
  • Chemical stability of the standard.
  • Transpiration losses of the standard.
  • Human error while using the standard.

Chemical stability is typically not a factor. After a year, your standard is not going to explode or precipitate out of solution. Under the right conditions, most standards are good indefinitely.

Transpiration losses cannot be prevented. All solutions transpire -- the longer the solution exists, the more concentrated it becomes over time.

Human error is really what an expiration is trying to keep to a minimum. It is uncontrollable and inevitable. A 1 year expiration date provides a standardized window of time in which the customer can safely assume that, with proper care, the standard will remain accurate. However, it remains an assumption -- there are no guarantees that the standard will remain accurate for the duration of that year.

As a manufacturer of standards, we are part of a scientific group in which dangerous marketing tactics should not be permitted. These ploys undermine the integrity of our industry -- an industry in which a single mistake can cause a chain of errors through several high-tech fields. It is irresponsible to market standards by half-truths, hiding negative results and confusing the numbers. Protect your interests as a consumer and always remember:

If it sounds too good to be true, it probably is.

The above information was taken from Expiration Facts You Should Know.

More Information:

» Shelf Life vs. Expiration Date
» Container Transpiration

Articles Online  more articles »

Calibration Curve and Standard Additions Techniques
Part ten of our ICP Operations guide covers calibration technique options for ICP measurements including calibration curve and standard additions.

Internal Standardization and Isotope Dilution
Part eleven of our ICP Operations guide is a continuation of part ten's discussion of standard additions. The topics of internal standardization and IDMS are also introduced.

Trace Metal Analysis of Air Condensate
Dr. Gaines explains why nitric acid is used to prepare air condensate samples and offers additional information on the topic.

Matrices for Soil Preparation
Dr. Gaines recommends a couple of matrices that will work well for soil preparations that involve Si.

Joke of the Month  more humor »

A neutron walks into a bar. He asks the bartender, "How much for a beer?" The bartender offers him a warm smile and says, "For you, no charge".

Element of the Month
Gold

Analytical Periodic Table

Storage & Handling:  Keep tightly sealed when not in use. Store and use at 20 ± 4°C. Do not pipet from container. Do not return portions removed for pipetting to container.

Chemical Compatibility:  Stable in HCl, and HNO3, as the chloride complex. Avoid basic media. Stable with most metals and inorganic anions in acidic media.

Stability:  2-100 ppb levels. 2-10 ppb Au is stable for ≤ 1 day maximum in 1% HNO3 / LDPE container. 100 ppb is stable for ≤ 2 days maximum in 1% HNO3 / LDPE container. 1-10,000 ppm solutions chemically stable for years in 10% HCl / LDPE container.

Au Containing Samples (Preparation & Solution):  Metal (aqua regia); Oxides (soluble in HCl); Ores (dissolve in HCl / HNO3).

Excerpt from Inorganic Venture's Analytical Periodic Table: Includes detailed analytical data for more than 70 elements.
 
Elemental Wordplay
Rearrange the elemental symbols to solve the riddle. Clues appear in quotes.

August's riddle...

Monetarily, "37¢" reflects the standard rate of ______ which includes...

    - Tantalum
    - Phosphorus
    - Germanium
    - and Osmium

(answer at bottom of page)
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 Wordplay answer:  Postage (P,Os,Ta,Ge)
 The IV Line · News from the Lab  · August 2004 (volume 9)
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Lakewood, NJ 08701

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