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Reliable Measurements

Tech Center - New Additions
ICP: Applying F Test Results   · NEW ·

Dr. Gaines offers advice regarding how to apply an F Test to the control chart results with respect to ICP-OES.
Sample Preparation Guide: Titanium   · NEW ·

The tenth installment of our Sample Preparation Guide reviews detailed preparation tips for samples containing Titanium.
ICP Operations Guide

A clear 16-part online guide intended for anyone preparing samples and standards for measurement using ICP. Topics cover many day-to-day tasks required by all operators.
Reliable Measurements: A Guidebook for Trace Analysts

An essential 17-part online guide for chemical analysts. Topics cover all phases of sample collection, preparation, measurement, and data analysis.
Elements with something to say...
Inorganic Ventures' Analytical Periodic Table
Analytical Periodic Table
Silicon Silicon (Si)
Atomic Weight: 28.086
Form in Soln: Si(OH)x(F)y2-
Click for more
Osmium Osmium (Os)
Atomic Weight: 190.2
Form in Soln: OsCl62-
Click for more
Mercury Mercury (Hg)
Atomic Weight: 200.59
Form in Soln: Hg(OH)(aq)1+
Click for more
Elemental Wordplay
Rearrange the elemental symbols to solve the riddle. Clues appear in quotes.

What "seasonal wind" is composed of...

    - 2 parts Nitrogen
    - 2 parts Oxygen
    - Molybdenum
    - and Sulfur?

answer ]
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  Spectroscopy

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Top 10 Unstable Elements
• Ppb stability study  Full article ]

View graphs
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Elements studied at the ppb level in LDPE bottles.

1.  Mercury (Hg) - not stable long enough to measure
2.  Gold (Au)
3.  Silver (Ag)
4.  Palladium (Pd)
5.  Platinum (Pt)
6.  Tantalum (Ta)
7.  Iridium (Ir)
8.  Molybdenum (Mo)
9.  Tin (Sn)
10.  Hafnium (Hf)

Container Transpiration
• Facts about your bottles  Full article ]

•  Transpiration occurs around the bottle opening and not through the bottle as previously thought.
•  Taping the bottle has no influence upon the transpiration rate.
•  Bottles that are half full and opened periodically have the highest transpiration rate.
•  Opening the bottle periodically greatly increases the transpiration rate.
•  Smaller bottles transpire faster.
•  30 ml bottles can not have a 1 year expiration date if certified to an uncertainty of ≤ ±0.6 % relative.
•  Transpiration Controlled Technology™ (TCT) totally eliminates transpiration.

Everyday Contaminants
• Contamination from the analyst  Full article ]

1.  Sweat contains Ca, Mg, Pb, K, NH4+ , SO4-2, PO4-3, and Cd (for those who smoke).
2.  Cosmetics can contain high concentrations of Al, Be, Ca, Cu, Cr, K, Fe, Mn, Ti, and Zn.
3.  Some hair dyes contain Pb(OAC)2.
4.  Dandruff shampoo can contain significant levels of Se.
5.  Eye make-up may contain Hg as a preservative.
6.  Calamine lotion is almost pure ZnO.
7.  Watches and jewelry contain an assortment of elements and should not be worn in the laboratory.

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